A New Synthetic Route to Heteroanthracenes
Glukhacheva V.S., Il'yasov S.G., Obraztsov A.A., Gatilov Y.V., Eltsov I.V.
European Journal of Organic Chemistry, 2018, Issue 10, Pages 1265-1273.

DOI: 10.1002/ejoc.201701689

Примеры ссылок для цитирования публикации:

Glukhacheva, V. S., Il'yasov, S. G., Obraztsov, A. A., Gatilov, Y. V. and Eltsov, I. V. (2018), A New Synthetic Route to Heteroanthracenes. Eur. J. Org. Chem., 2018: 1265-1273. doi:10.1002/ejoc.201701689

Идентификаторы:

DOI: 10.1002/ejoc.201701689
WOS: WOS:000427473000011
Scopus: 2-s2.0-85043693108
РИНЦ: 32598527

Реферат:
In this report, we describe the synthesis of 2,3,4a,6,7,8a,9,10‐octaaza‐4,8‐dioxo‐3,4,4a,7,8,8a,9,9a,10,10a‐decahydroanthracene, an octaaza derivative of reduced anthracene, through the reaction of glyoxal bis(nitrosemicarbazone) with glyoxal bis(hydrazone) in aqueous medium at 70 °C as well as by the hydrolytic decomposition of glyoxal bis(nitrosemicarbazone) in aqueous medium at 70 °C in a one‐pot transformation. The structure of the resultant compound was confirmed by physicochemical analytical methods and X‐ray diffraction. We also obtained the first representative of the cyclic monohydrazone dimer 1,2,4,5,8,9,11,12‐octaazacyclotetradeca‐5,7,12,14‐tetraene‐3,10‐dione, which exists as lactam and lactim tautomers, through the reaction of glyoxal bis(nitrosemicarbazone) with glyoxal bis(hydrazone) in alkaline aqueous medium.